POLYCYCLIC AROMATIC HYDROCARBON AND PETROLEUM HYDROCARBON CONTAMINATION IN SEDIMENT FROM THE NEWARK BAY ESTUARY, NEW-JERSEY

The presence of numerous industrial and municipal sources such as former creosote wood preserving facilities, petroleum storage and refinery facilities, paint and chemical manufacturers, combined sewer overflows, and sewage treatment facilities along the shores of Newark Bay, New Jersey and its major tributaries suggests the potential for widespread contamination by polycyclic aromatic hydrocarbons (PAHs) and petroleum hydrocarbons. In this study, the concentrations and distributions of 19 PAHs and total extractable petroleum hydrocarbon (TEPH) were determined in 213 sediment samples obtained from 58 sediment cores collected between November 1998 and March 1993 from the Arthur Kill, Elizabeth River, Hackensack River, Kill Van Kull, Newark Bay, Upper New York Bay, and Rahway River. Chronological profiles of PAH and TEPH deposition from pre-1930 to the present were determined in each sediment core using Cs-137 and (210)pb radioisotope measurements. The concentrations of total PAHs (tPAH) and individual PAHs were compared to National Oceanic and Atmospheric Administration (NOAA) benchmark sediment effects-range median (ER-M) values. The objectives of this study were to: (a) determine the spatial and temporal distributions of PAHs in sediments; (b) identify their possible sources; and (c) assess the potential for sediment toxicity within the estuary. The results indicate elevated concentrations of PAHs and TEPH in surface and buried sediments throughout the estuary, partic ularly in the Elizabeth River, the Arthur Kill, acid in the Passaic River above the Dundee Dam and below the Jackson Street Bridge. Sediments collected from ship berths at Port Newark and Port Elizabeth in Newark Bay were also found to contain elevated levels of PAHs and TEPH. The concentrations of PAHs and TEPH in sediment generally increase with depth throughout the estuary. Comparisons to NOAA ER-M values indicate that the concentrations of many PAHs in surface and buried sediments at several locations in the estuary pose a significant hazard to aquatic organisms. Radiodating of sediment cores reveals that the highest concentrations of PAHs, and the greatest potential hazards to aquatic biota, occur in sediments deposited during the 1950s. Although the major inputs of PAHs are probably combustion sources and urban runoff entering the estuary through combined sewer overflows and storm drains, the unusually high concentrations of PAHs and TEPH found in some sediments may be best explained by point source inputs or catastrophic oil spills.