PHOTOINDUCED INTERMOLECULAR AND INTRAMOLECULAR ELECTRON-TRANSFER REACTIONS OF [60]FULLERENE AND A TERTIARY AMINE - FORMATION OF THE CYCLOADDUCT N-ETHYL-TRANS-2',5'-DIMETHYLPYRROLIDINO[3',4'/1,2][60]FULLERENE

被引：93

作者：

LAWSON, GE ^{[1
]}

KITAYGORODSKIY, A ^{[1
]}

MA, B ^{[1
]}

BUNKER, CE ^{[1
]}

SUN, YP ^{[1
]}

机构：

[1] CLEMSON UNIV,HOWARD L HUNTER CHEM LAB,DEPT CHEM,CLEMSON,SC 29634

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002225

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoreduction of [60]fullerene by triethylamine results in the formation of a cycloadduct N-ethyl-trans-2',5'-dimethylpyrrolidino[3',4':1,2][60]fullerene, which is probably due to sequential intermolecular and intramolecular processes and argues strongly for the presence of ion pairs as intermediates in a room temperature toluene solution.

引用

页码：2225 / 2226

页数：2