Reactive scattering of hydrogen and deuterium atoms from halogen molecules

被引：46

作者：

Grosser, J. ^{[1
]}

Haberland, H. ^{[1
]}

机构：

[1] Univ Freiburg, Fak Phys, D-7800 Freiburg, Germany

来源：

CHEMICAL PHYSICS | 1973年 / 2卷 / 03期

关键词：

D O I：

10.1016/0301-0104(73)80037-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Angular distributions of H and D atoms reactively scattered from the halogen molecules Cl-2, Br-2, ICl, IBr have been measured. The angular distributions are backwards or sideways peaked. No isotope effect on the angular distribution was found. The total reactive cross sections are 1 - 10 A(2), and for D atoms they are about 50% larger than for H atoms. A simple direct interaction model is proposed, which shows good agreement with the experimental results.

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页码：342 / 351

页数：10

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