REVISED ASSIGNMENT OF THE ELECTRON-SPIN RESONANCE-SPECTRUM OBTAINED BY PHOTOLYSIS OF TETRASULFUR TETRANITRIDE-BIS(NORBORNENE)

被引:23
作者
ROLFE, S
GRILLER, D
INGOLD, KU
SUTCLIFFE, LH
机构
[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R6,ONTARIO,CANADA
[2] UNIV LIVERPOOL,DONNAN LABS,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND
关键词
D O I
10.1021/jo01334a015
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Isotopic labeling with 33S has been used to show that the radical obtained by photolysis of tetrasulfur tetranitride-bis(norbornene) and by the thermal reaction of tetrasulfur dinitride with norbornene is exo-1, 2-norbornyl-l', 3', 2'-dithiazolidin-2'-yl. Several analogous radicals have been prepared and it is suggested that S4N4 adducts with unsaturated hydrocarbons may provide a starting point for the synthesis of compounds containing the 1, 3, 2-dithiazolidine ring system. © 1979, American Chemical Society. All rights reserved.
引用
收藏
页码:3515 / 3519
页数:5
相关论文
共 39 条
[1]  
ADAMIC K, 1971, J AM CHEM SOC, V93, P903
[2]   PREPARATION OF MILLIGRAM QUANTITIES OF TETRASULFUR TETRANITRIDE AND TETRASULFUR DINITRIDE BY A METHOD SUITABLE FOR ISOTOPIC LABELING [J].
APTER, S ;
CARRUTHERS, M ;
SUTCLIFFE, LH .
INORGANICA CHIMICA ACTA, 1978, 31 (02) :L455-L456
[3]   ELECTRON-SPIN RESONANCE STUDY OF DIALKYLAMINOTHIYL (R2NS.), DIALKYLAMINOSULFINYL (R2NSO), AND ALKYL(SULFINYL)AMINYL [RNS(O)X] RADICALS - RADICAL-ADDITION TO N-SULFINYLAMINES [J].
BABAN, JA ;
ROBERTS, BP .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (07) :678-683
[4]   CHEMISTRY OF TRISULFENAMIDES [N(SR)3] .1. PREPARATION, THERMAL-DECOMPOSITION, AND REACTIONS OF TRIBENZENESULFENAMIDE [N(SPH)3] [J].
BARTON, DHR ;
BLAIR, IA ;
MAGNUS, PD ;
NORRIS, RK .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (10) :1031-1036
[5]  
Becke-Goehring M., 1959, PROGR INORG CHEM, V1, P207
[6]   TETRASULFUR TETRANITRIDE AN INORGANIC DIENE [J].
BECKEGOEHRING, M ;
SCHLAFER, D .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1968, 356 (5-6) :234-+
[7]   2,2,6,6-TETRAMETHYLPIPERIDYL-1-THIYL - A STABLE NEW RADICAL [J].
BENNETT, JE ;
SIEPER, H ;
TAVS, P .
TETRAHEDRON, 1967, 23 (04) :1697-&
[8]   REACTION OF TETRASULFUR TETRANITRIDE WITH STRAINED OLEFINS [J].
BRINKMAN, MR ;
ALLEN, CW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) :1550-&
[9]   NEW CLASS OF THIYL FREE-RADICALS (1-AZIRIDYL-THIYLS [J].
BRINKMAN, MR ;
SUTCLIFFE, LH .
JOURNAL OF MAGNETIC RESONANCE, 1977, 28 (02) :263-270
[10]   RADICAL ADDITIONS TO DI-TERT-BUTYLSULFUR DIIMIDE AND DI-TERT-BUTYLCARBODIIMIDE [J].
BRUNTON, G ;
TAYLOR, JF ;
INGOLD, KU .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (16) :4879-4882