REVISED ASSIGNMENT OF THE ELECTRON-SPIN RESONANCE-SPECTRUM OBTAINED BY PHOTOLYSIS OF TETRASULFUR TETRANITRIDE-BIS(NORBORNENE)

被引：23

作者：

ROLFE, S

GRILLER, D

INGOLD, KU

SUTCLIFFE, LH

机构：

[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R6,ONTARIO,CANADA

[2] UNIV LIVERPOOL,DONNAN LABS,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 20期

关键词：

D O I：

10.1021/jo01334a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isotopic labeling with 33S has been used to show that the radical obtained by photolysis of tetrasulfur tetranitride-bis(norbornene) and by the thermal reaction of tetrasulfur dinitride with norbornene is exo-1, 2-norbornyl-l', 3', 2'-dithiazolidin-2'-yl. Several analogous radicals have been prepared and it is suggested that S4N4 adducts with unsaturated hydrocarbons may provide a starting point for the synthesis of compounds containing the 1, 3, 2-dithiazolidine ring system. © 1979, American Chemical Society. All rights reserved.

引用

页码：3515 / 3519

页数：5

共 39 条

[11] NITROGEN-CENTERED FREE-RADICALS .9. EASE OF FORMATION OF THIONITROXIDE RADICALS [J].