A SIMPLE LABORATORY PROCEDURE FOR PREPARATION OF (1-METHYLETHENYL)OXIRANE (3,4-EPOXYISOPRENE)

被引：28

作者：

HARWOOD, LM

CASY, G

SHERLOCK, J

机构：

[1] Dyson Perrins Laboratory, University of Oxford, South Parks Road

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 09期

关键词：

D O I：

10.1080/00397919008052839

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This Communication describes a convenient procedure for the preparation of pure 3,4-epoxyisoprene (1). Reaction of methacrolein with the ylide prepared by reaction of trimethylsulphonium methanesulphonate with powdered sodium hydroxide suspended in dichloromethane furnishes pure material after simple distillation. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1287 / 1292

页数：6

共 23 条

[11] A STEREOCONTROLLED TOTAL SYNTHESIS OF OPTICALLY-ACTIVE (R,R)-PHYTOL [J].