ON THE TRANSITION-STATE FOR CLAYZIC-CATALYZED FRIEDEL-CRAFTS REACTIONS UPON ANISOLE

被引：43

作者：

CORNELIS, A

LASZLO, P

WANG, S

机构：

[1] UNIV LIEGE SART TILMAN,CHIM FINE INTERFACES LAB,B-4000 LIEGE,BELGIUM

[2] ECOLE POLYTECH,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 24期

关键词：

UNIMODAL KINETICS; ACTIVATION PARAMETERS; CHEMISORPTION; LEWIS ACID;

D O I：

10.1016/S0040-4039(00)79244-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The activation parameters point to a strongly organized transition state on the catalyst surface, with partial breaking of the carbon-leaving group bond in the BnCl or in the Ac2O reagent.

引用

页码：3849 / 3852

页数：4

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