RED-AL PROMOTED INTRAMOLECULAR REDUCTIVE CLEAVAGE OF BENZYL 4-HYDROXY-2-BUTENYL ETHER STRUCTURES - A CONCISE PREPARATION OF POLYOL CHIRAL BUILDING-BLOCKS

被引：23

作者：

HATAKEYAMA, S ^{[1
]}

SATOH, K ^{[1
]}

TAKANO, S ^{[1
]}

机构：

[1] UNIV TOKUSHIMA,FAC PHARMACEUT SCI,TOKUSHIMA 770,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)60143-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new concise and practical method for the preparation of polyol chiral building blocks has been developed based on the finding of unprecedented Red-Al promoted intramolecular reductive cleavage of benzyl 4-hydroxy-2-butenyl ether structures and the synthetic utility has been demonstrated by accomplishment of an expeditious synthesis of the compactin lactone derivative.

引用

页码：7425 / 7428

页数：4

共 33 条

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