THE EFFECT OF A TERT-BUTYLDIMETHYLSILYL SUBSTITUENT ON THE 1,5-ASYMMETRIC INDUCTION FOUND IN REACTIONS OF 4-ALKOXYALLYLSTANNANES AND 5-ALKOXYALLYLSTANNANES WITH ALDEHYDES AND IMINES

被引：28

作者：

BRADLEY, GW ^{[1
]}

HALLETT, DJ ^{[1
]}

THOMAS, EJ ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 10期

关键词：

D O I：

10.1016/0957-4166(95)00338-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 4-benzyloxy- and 4-tert-butyldimethylsilyloxy-pent-2-enylstannanes 6a and 6b show different stereoselectivity in tin(IV) chloride promoted reactions with aldehydes and imines.

引用

页码：2579 / 2582

页数：4

共 6 条

[1] 1,5-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN (ALKOXYALLYL)STANNANES AND ALDEHYDES - INFLUENCE OF THE LEWIS-ACID AND O-SUBSTITUENT [J].

CAREY, JS ;

COULTER, TS ;

THOMAS, EJ .

TETRAHEDRON LETTERS, 1993, 34 (24) :3933-3934

[2]

CAREY JS, 1992, SYNLETT, P585

[3] 1,5-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN 4-ALKOXY-PENT-2-ENYL(TRIBUTYL)STANNANES AND 5-ALKOXY-PENT-2-ENYL(TRIBUTYL)STANNANES AND ACHIRAL 1-ALKOXYCARIBONYLIMINES [J].

HALLETT, DJ ;

THOMAS, EJ .

TETRAHEDRON-ASYMMETRY, 1995, 6 (10) :2575-2578

[4] REMOTE ASYMMETRIC INDUCTION IN REACTIONS BETWEEN 4-BENZYLOXYPENT-2-ENYL(TRIBUTYL)STANNANE AND 5-BENZYLOXYPENT-2-ENYL(TRIBUTYL)STANNANE AND CHIRAL IMINES PREPARED FROM BUTYL GLYOXYLATE [J].

HALLETT, DJ ;

THOMAS, EJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :657-658

[5] 1,5-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN DELTA-ALKOXYALLYLSTANNANES AND ALDEHYDES INDUCED BY TIN (IV) CHLORIDE [J].

MCNEILL, AH ;

THOMAS, EJ .

TETRAHEDRON LETTERS, 1990, 31 (43) :6239-6242

[6]

MCNEILL AH, 1994, SYNTHESIS-STUTTGART, P207

← 1 →