SYNTHESIS AND MOLECULAR-STRUCTURE OF CHLORO(3-THIAPENTANE-1,5-DITHIOLATO)OXORHENIUM(V)

被引：57

作者：

FIETZ, T

SPIES, H

PIETZSCH, HJ

LEIBNITZ, P

机构：

[1] FORSCHUNGSZENTRUM ROSSENDORF EV,INST BIOANORGAN & RADIOPHARMAZEUT CHEM,D-01314 DRESDEN,GERMANY

[2] BUNDESANSTALT MATFORSCH,D-12489 BERLIN,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 231卷 / 1-2期

关键词：

RHENIUM COMPLEXES; OXO COMPLEXES; POLYDENTATE LIGAND COMPLEXES; CRYSTAL STRUCTURES;

D O I：

10.1016/0020-1693(94)04351-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [BzEt(3)N][ReOCl4] (1) with 0.9 equiv, of 3-thiapentane 1,5-dithiol (HSSSH) in chloroform delivers [ReO(SSS)Cl] (2). The chloro ligand can be substituted by mercaptides when 2 is heated with an excess of a mercaptane, e.g. C2H5SH, in acetonitrile. Single crystal X-ray analysis of 2 shows square-pyramidal geometry.

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页码：233 / 236

页数：4

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