2 CARBON HOMOLOGATION OF CARBOXYLIC-ACIDS VIA CARBON RADICALS GENERATED FROM THE ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE - SYNTHESIS OF CN+2 ALPHA-KETO-ACIDS FROM CN ACIDS - (THE 3 CARBON PROBLEM)

被引：16

作者：

BARTON, DHR

CHERN, CY

JASZBERENYI, JC

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61177-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of olefins containing a three carbon atom chain with carbon radicals generated from carboxylic acids furnishes adducts that are precursors of the corresponding two carbon atom longer alpha-keto-acids. The keto-acids are furnishes in high overall yield.

引用

页码：5017 / 5020

页数：4

共 44 条

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