LASER-INDUCED PHOTOLYSIS OF IODOFORM

被引：34

作者：

SPEISER, S

KIMEL, S

机构：

[1] Department of Chemistry, Technion, Israel Institute of Technology, Haifa

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 12期

关键词：

D O I：

10.1063/1.1671989

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iodoform dissolved in various solvents was irradiated with a Q-switched ruby laser. The two-photon photolysis was studied by measuring the concentration of the liberated iodine. Different two-photon absorption cross sections were obtained for iodoform in different solvents. The major solvent effect was found to be due to the self-focusing properties of the medium. After appropriate corrections for this effect, good agreement was obtained between measured and calculated cross sections. It was also found that the self-focusing length of a liquid could be determined chemically" from the degree of photolysis."

引用

页码：5614 / &

共 30 条

[21] GIANT-PULSE-LASER FLASH PHOTOLYSIS OF PHTHALOCYANINE VAPOR [J].