NOVEL TRITERPENE-DERIVED HYDROCARBONS OF ARBORANE FERNANE SERIES IN SEDIMENTS .1.

被引：47

作者：

HAUKE, V

GRAFF, R

WEHRUNG, P

TRENDEL, JM

ALBRECHT, P

SCHWARK, L

KEELY, BJ

PEAKMAN, TM

机构：

[1] RHEIN WESTFAL TH AACHEN,LEHRSTUHL GEOL GEOCHEM & LAGERSTATTEN ERDOLS & KOHLE,W-5100 AACHEN,GERMANY

[2] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 19期

基金：

英国自然环境研究理事会;

关键词：

DES-A-ARBORA-5,7,9-TRIENE; 24,25-DINORARBORA-1,3,5(10),9(11)-TETRAENE; 24,25-DINORARBORA-1,3,5,7,9-PENTAENE; PENTACYCLIC TRITERPENE-DERIVED AROMATIC HYDROCARBONS; ISOLATION FROM SEDIMENTS AND STRUCTURAL IDENTIFICATION BY NMR SPECTROSCOPY;

D O I：

10.1016/S0040-4020(01)88471-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three aromatic polycyclic hydrocarbons were isolated from Eocene shales and the Permian Kupferschiefer. and their molecular structures established by 1D and 2D NMR spectroscoPY. These compounds (des-A-arbora-5,7,9-triene; 24,25-dinorarbora-1,3,5(10),9(11)-tetraene; 24,25-dinorarbora-1,3,5,7,9-pentaene) derive from microbial transformations of pentacyclic triterpenes oxygenated at C-3 belonging to the arborane or fernane families.

引用

页码：3915 / 3924

页数：10

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