TIME EVOLUTION OF VERY HIGH RYDBERG STATES OF LARGE AROMATIC-MOLECULES - A KINETIC-ANALYSIS

被引:43
作者
EVEN, U [1 ]
BENNUN, M [1 ]
LEVINE, RD [1 ]
机构
[1] HEBREW UNIV JERUSALEM,FRITZ HABER RES CTR MOLEC DYNAM,IL-91904 JERUSALEM,ISRAEL
关键词
D O I
10.1016/0009-2614(93)87047-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A long (miroseconds) and shorter (approximately 1 mus) decay channel are resolved in the time evolution of very high Rydberg states of large aromatic molecules. A simple kinetic analysis is presented and applied to the very detailed results available for tetracene. It is concluded that under our experimental conditions the time evolution is due to intramolecular processes. The various possible decay channels are discussed.
引用
收藏
页码:416 / 422
页数:7
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