A NOVEL TYPE OF STEREOISOMERISM IN CALIX[4]ARENE-BASED CARCEPLEXES

被引:172
作者
TIMMERMAN, P [1 ]
VERBOOM, W [1 ]
VANVEGGEL, FCJM [1 ]
VANDUYNHOVEN, JPM [1 ]
REINHOUDT, DN [1 ]
机构
[1] UNIV TWENTE,ORGAN CHEM LAB,7500 AE ENSCHEDE,NETHERLANDS
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期
关键词
D O I
10.1002/anie.199423451
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Different orientations of the guest in the cavity of a carcerand lead to a new type of stereoisomerism, “carceroisomerism”. The structure of the host–guest compound (which is shown on the cover of this issue) and its dynamic behavior was studied in detail by NMR methods. Such compounds could perhaps find application as molecular switches for electronic devices. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:2345 / 2348
页数:4
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