SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A UNIQUE OCTANUCLEAR BISMUTH(III) THIOSALICYLATE COMPLEX WITH A DISK-LIKE CLUSTER CORE

被引：19

作者：

ASATO, E ^{[1
]}

KATSURA, K ^{[1
]}

ARAKAKI, T ^{[1
]}

MIKURIYA, M ^{[1
]}

KOTERA, T ^{[1
]}

机构：

[1] KWANSEI GAKUIN UNIV, SCH SCI, DEPT CHEM, NISHINOMIYA, HYOGO 662, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2123

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The octanuclear bismuth(III) thiosalicylate complex, [Bi-8(tsal)(12)(DMF)(6)](DMF)(6) (H(2)tsal = thiosalicylic acid, DMF = N,N'-dimethylformamide), has been prepared and structurally characterized. The single crystal X-ray structure analysis has demonstrated that the eight Bi atoms form a disk-like cluster core and that each lone pair of two Bi atoms as the asymmetric unit is stereochemically activated.

引用

页码：2123 / 2126

页数：4

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