A MOSSBAUER AND X-RAY DIFFRACTION STUDY ON CATION DISTRIBUTION IN FEAL2O4

被引:60
作者
YAGNIK, CM
MATHUR, HB
机构
[1] National Chemical Laboratory, Poona
来源
JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS | 1968年 / 1卷 / 02期
关键词
D O I
10.1088/0022-3719/1/2/320
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The Mössbauer spectrum of FeAl2O4 consists of three absorption peaks at 0, 1.46 and 2.56 mm s-1 relative to a 57Co/Cu source. The spectrum can be resolved into two quadrupole-split spectra. The outer pair of lines corresponds to a quadrupole splitting of 2.76±0.10 mm s-1 and an isomer shift of 1.52±0.10 mm s-1 and may be attributed to the Fe2+ ions at the B sites. The inner doublet with a quadrupole splitting of 1.39±0.10 mm s-1 and an isomer shift of 1.10±0.10 mm s-1 can be attributed to the Fe2+ ions at the A sites. The degree of inversion x was determined from the relative areas under the two spectra to be 23±2%. This is in agreement with the value of 25% determined from the intensities of the X-ray diffraction powder pattern.
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页码:469 / &
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