POLYCHLOROMETHYLSTYRENE MICROSPHERES - SYNTHESIS AND CHARACTERIZATION

被引:87
作者
MARGEL, S
NOV, E
FISHER, I
机构
[1] Department of Chemistry, Bar‐Ilan University, Rmat-Gan
关键词
D O I
10.1002/pola.1991.080290307
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis and characterization of polychloromethylstyrene microspheres are described. The effect of various factors, e.g., monomer concentration, surfactant concentration, solvents, crosslinker, etc., on the yield, diameter, and size distribution of these microspheres was elucidated. Conditions to covalently bind various primary amino ligands to these microspheres in aqueous solution were also established. The possible routes to modify the surface of these microspheres to obtain functional groups other than chloromethyl are discussed.
引用
收藏
页码:347 / 355
页数:9
相关论文
共 24 条
[21]   PREPARATION OF LARGE-PARTICLE-SIZE MONODISPERSE LATEXES IN SPACE - POLYMERIZATION KINETICS AND PROCESS-DEVELOPMENT [J].
VANDERHOFF, JW ;
ELAASSER, MS ;
MICALE, FJ ;
SUDOL, ED ;
TSENG, CM ;
SILWANOWICZ, A ;
KORNFELD, DM ;
VICENTE, FA .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 1984, 5 (3-4) :231-246
[22]  
VANDERHOFF JW, 1964, AM CHEM SOC DIV ORG, V24, P223
[23]   FUNCTIONALIZATION OF POLYSTYRENE .2. SYNTHESIS OF CHELATING POLYMERS BY ALKYLATION OF 4-AMINOMETHYLPOLYSTYRENE [J].
WARSHAWSKY, A ;
DESHE, A ;
ROSSEY, G ;
PATCHORNIK, A .
REACTIVE POLYMERS, 1984, 2 (04) :301-314
[24]  
ZUIKOV AV, 1979, ACTA POLYM, V30, P503