A NEW METHOD FOR NITRATION OF ALKENES TO ALPHA,BETA-UNSATURATED NITROALKENES

被引：45

作者：

HWU, JR ^{[1
]}

CHEN, KL ^{[1
]}

ANANTHAN, S ^{[1
]}

机构：

[1] ACAD SINICA,INST CHEM,ORGANOSILICON & SYNTH LAB,TAIPEI 11529,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha,beta-Unsaturated nitroalkenes were synthesized in 54-99% yields by sonication of a chloroform solution containing the corresponding alkenes, NaNO2 (10 equiv.), Ce(NH4)(2)(NO3)(6) (2.0 equiv.), and acetic acid (12 equiv.) in a sealed tube at 25-73 degrees C.

引用

页码：1425 / 1426

页数：2

共 31 条

[1] FORMATION AND THERMODYNAMIC PROPERTIES OF NITROUS ACID VAPOUR [J].

ASHMORE, PG ;

TYLER, BJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (MAR) :1017-&

[2] CHEMOSELECTIVE SYNTHESIS OF FUNCTIONALIZED CONJUGATED NITROALKENES [J].

BALLINI, R ;

CASTAGNANI, R ;

PETRINI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (07) :2160-2162

[3] CONJUGATED NITROALKENES - VERSATILE INTERMEDIATES IN ORGANIC-SYNTHESIS [J].

BARRETT, AGM ;

GRABOSKI, GG .

CHEMICAL REVIEWS, 1986, 86 (05) :751-762

[4] HETEROSUBSTITUTED NITROALKENES IN SYNTHESIS [J].

BARRETT, AGM .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (01) :95-127

[5]

Braun S., 1988, CARBON 13 NMR SPECTR, P292

[6]

de Jonge C. R. H. I., 1986, ORGANIC SYNTHESES OX

[7] A GENERAL-METHOD FOR THE PREPARATION OF 2,2-DISUBSTITUTED 1-NITROALKENES [J].

DENMARK, SE ;

MARCIN, LR .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (15) :3850-3856

[8] NITROALKENE [4+2] CYCLOADDITION AS A GENERAL AND STEREOSELECTIVE ROUTE TO THE SYNTHESIS OF 3,3-DISUBSTITUTED AND 3,4-DISUBSTITUTED PYRROLIDINES [J].

DENMARK, SE ;

MARCIN, LR .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (15) :3857-3868

[9]

FELLUGA F, 1992, J CHEM RES-S, P86

[10]

FELLUGA F, 1992, J CHEM RES M, P401

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