A NEW METHOD FOR NITRATION OF ALKENES TO ALPHA,BETA-UNSATURATED NITROALKENES

被引：45

作者：

HWU, JR ^{[1
]}

CHEN, KL ^{[1
]}

ANANTHAN, S ^{[1
]}

机构：

[1] ACAD SINICA,INST CHEM,ORGANOSILICON & SYNTH LAB,TAIPEI 11529,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha,beta-Unsaturated nitroalkenes were synthesized in 54-99% yields by sonication of a chloroform solution containing the corresponding alkenes, NaNO2 (10 equiv.), Ce(NH4)(2)(NO3)(6) (2.0 equiv.), and acetic acid (12 equiv.) in a sealed tube at 25-73 degrees C.

引用

页码：1425 / 1426

页数：2

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