ADSORPTION METHODS TO STUDY MICROPOROSITY IN COALS AND CARBONS - A CRITIQUE

被引：234

作者：

MARSH, H

机构：

[1] Univ of Newcastle upon Tyne, Newcastle upon Tyne, Engl, Univ of Newcastle upon Tyne, Newcastle upon Tyne, Engl

来源：

CARBON | 1987年 / 25卷 / 01期

关键词：

COAL; -; Porosity;

D O I：

10.1016/0008-6223(87)90039-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article discusses interpretation of adsorption data from microporous coals and carbons. Problems associated with activated diffusion, molecular sieve effects, cooperative adsorption effects, the use of polar adsorbates and understanding of limitations and value of theoretical adsorption equations are assessed. The Dubinin-Radushkevich and Dubinin-Astakhov equations appear superior to Langmuir or BET equations in terms of differentiating and describing the microporosities.

引用

页码：49 / 58

页数：10