NUMERICAL-SOLUTION OF A MODIFIED POISSON-BOLTZMANN EQUATION IN ELECTRIC DOUBLE-LAYER THEORY

被引：19

作者：

BHUIYAN, LB ^{[1
]}

OUTHWAITE, CW ^{[1
]}

LEVINE, S ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT MATH,MANCHESTER M13 9PL,LANCASHIRE,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)85026-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A modified Poisson-Boltzmann equation in the diffuse part of the electric double layer is solved using a quasi-linearisation technique. A damped oscillatory behaviour is demonstrated in the mean electrostatic potential and in the ion-wall distribution functions for a fixed wall potential at relatively high electrolyte concentrations. © 1979.

引用

页码：321 / 324

页数：4

共 12 条

[1] LINEARIZED POTENTIAL EQUATION FOR INTERFACIAL REGION IN AN UNSYMMETRICAL ELECTROLYTE [J].

BELL, GM ;

RANGECROFT, PD .

MOLECULAR PHYSICS, 1972, 24 (02) :255-+

[2] THEORY OF ELECTRIFIED INTERFACES [J].

BLUM, L .

JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (02) :136-147

[3] CALCULATION OF THERMODYNAMIC PROPERTIES OF ELECTROLYTE SOLUTIONS USING A MODIFIED POISSON-BOLTZMANN EQUATION [J].

BURLEY, DM ;

HUTSON, VCL ;

OUTHWAITE, CW .

MOLECULAR PHYSICS, 1972, 23 (05) :867-+

[4] A Contribution to the Theory of Electrocapillarity [J].

Chapman, David Leonard .

PHILOSOPHICAL MAGAZINE, 1913, 25 (148) :475-481

[5]

Gouy G., 1917, ANN PHYS-BERLIN, V9, P129, DOI 10.1051/anphys/191709070129

[6]

Gouy M., 1910, J PHYS THEOR APPL, V9, P457, DOI DOI 10.1051/JPHYSTAP:019100090045700

[7]

HENDERSON DA, UNPUBLISHED

[8] On the Theory of Strong Electrolyte Solutions [J].

Kirkwood, John G. .

JOURNAL OF CHEMICAL PHYSICS, 1934, 2 (11)

[9] COMPARISON OF THEORIES OF AQUEOUS ELECTRIC DOUBLE-LAYER AT A CHARGED PLANE INTERFACE [J].

LEVINE, S ;

OUTHWAITE, CW .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1978, 74 :1670-1689

[10] AN INTERIONIC ATTRACTION THEORY APPLIED TO THE DIFFUSE LAYER AROUND COLLOID PARTICLES .1. [J].

LOEB, AL .

JOURNAL OF COLLOID SCIENCE, 1951, 6 (01) :75-91

← 1 2 →