COPPER(II) AND NICKEL(II) COMPLEXES OF 2-FORMYLPYRIDINE 3-PIPERIDINYLCARBAZONE 3-HEXAMETHYLENEIMINYLCARBAZONE AND 3-AZABICYCLO[3.2.2]NONYLTHIOSEMICARBAZONE

被引：50

作者：

WEST, DX

OOMS, CE

SALEDA, JS

GEBREMEDHIN, H

LIBERTA, AE

机构：

[1] Department of Chemistry, Illinois State University, Normal, 61761, IL

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 05期

关键词：

D O I：

10.1007/BF00136373

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) and nickel(II) complexes of 2-formylpyridine 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo-[3.2.2]nonylthiosemicarbazones were prepared and characterized spectroscopically. H-1 and C-13 n.m.r. spectra of the thiosemicarbazones and a diamagnetic nickel(II) complex are reported, together with i.r., electronic and e.s.r. spectra of the metal complexes. The thiosemicarbazones and their copper(II) and nickel(II) complexes exhibit considerable growth inhibitory activity against Paecilomyces variotii, but show minimal activity against Aspergillus niger.

引用

页码：553 / 558

页数：6