WALL-JET ELECTRODE LINEAR SWEEP VOLTAMMETRY

被引：15

作者：

COMPTON, RG ^{[1
]}

FISHER, AC ^{[1
]}

LATHAM, MH ^{[1
]}

BRETT, CMA ^{[1
]}

BRETT, AMCFO ^{[1
]}

机构：

[1] UNIV COIMBRA,DEPT QUIM,P-3409 COIMBRA,PORTUGAL

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 21期

关键词：

D O I：

10.1021/j100200a028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Theory is presented which predicts the linear sweep voltametry behavior at the wall-jet electrode for a reversible couple. The scan rate and electrode geometry dependences are established, and hence the requirements for the measurement of true "steady state" hydrodynamic voltammograms are defined. Theory is found to be in good agreement with experiments conducted on the oxidation of the ferrocyanide anion in aqueous solution.

引用

收藏

页码：8363 / 8367

页数：5

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