CHROMIC MATERIALS .1. LIQUID-CRYSTALLINE BEHAVIOR AND ELECTROCHROMISM IN BIS(OCTAKIS-N-ALKYLPHTHALOCYANINATO)LUTETIUM(III) COMPLEXES

被引：104

作者：

KOMATSU, T

OHTA, K

FUJIMOTO, T

YAMAMOTO, I

机构：

[1] SHINSHU UNIV,DEPT FUNCT POLYMER SCI,MATSUMOTO,NAGANO 390,JAPAN

[2] EASTERN CO LTD,CHINO 391,JAPAN

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 04期

关键词：

D O I：

10.1039/jm9940400533

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel bis(phthalocyaninato)lutetium(III) complexes substituted with long n-alkyl chains have been synthesized. These complexes, 1a-c, show three kinds of discotic mesophase (D(hd), D(ob.d), and D(L). Also 1a-c display the three primary colours (red, green, blue) of electrochromism in their solutions. The solutions of oxidized species of 1a-c are nearly red, although those of conventional bis(phthalocyaninato)lutetium(III) complexes are orange.

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页码：533 / 536

页数：4

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