PREPARATION OF OPTICALLY PURE TRICARBONYLCYCLOHEXADIENYLIRON COMPLEXES - USE OF A TRIFLUOROMETHYL GROUP AS A REGIODIRECTOR DURING HYDRIDE ABSTRACTION

被引：34

作者：

PEARSON, AJ ^{[1
]}

GELORMINI, AM ^{[1
]}

PINKERTON, AA ^{[1
]}

机构：

[1] UNIV TOLEDO,DEPT CHEM,TOLEDO,OH 43606

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 02期

关键词：

D O I：

10.1021/om00038a065

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of optically pure 1-(trifluoromethyl)cyclohexa-1,3-diene-5,6-diol with Fe2(CO)9 proceeds stereospecifically to give the endo complex 4, which was characterized by single-crystal X-ray structure determination; the trifluoromethyl group in 4 is found to be an excellent regiodirector during hydride abstraction and dehydroxylation reactions of 4.

引用

页码：936 / 938

页数：3

共 15 条

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