JUNICEDRANOL, A SESQUITERPENE WITH A NOVEL CARBON SKELETON FROM JUNIPERUS-OXYCEDRUS SSP MACROCARPA

被引：14

作者：

BARRERO, AF

ALVAREZMANZANEDA, E

LARA, A

机构：

[1] Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 35期

关键词：

D O I：

10.1016/0040-4039(95)01228-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Junicedranol 1, a sesquiterpene with a novel carbon skeleton, has been isolated from the essential oil of the wood of Juniperus oxycedrus ssp. macrocarpa. The structure was determined by the analysis of 2D NMR spectra to be a 2,2,6,7-teaamethyl-tricycle[5.2.2.0(1.6)]undecane carbon skeleton. Its relative stereochemistry is proposed on the basis of NOESY. The absolute configuration was established by ''Mosher's method''.

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页码：6347 / 6350

页数：4

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