A NEW BONDING MODEL FOR OLEFINIC AND ACETYLENIC COMPLEXES OF TRANSITION METALS

被引:71
作者
NELSON, JH
WHEELOCK, KS
CUSACHS, LC
JONASSEN, HB
机构
[1] Richardson Chemistry Laboratories, Tulane University, New Orleans
关键词
D O I
10.1021/ja01053a019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Semiempirical one-electron molecular orbital calculations were performed for a series of platinum-acetylene and -olefin complexes. The results indicate that the Dewar-Chatt-Duncanson model can be modified and extended to include the acetylenic complexes. A consistent hybridization scheme, dp2, is developed to explain the chemical and physical properties of these complexes. © 1969, American Chemical Society. All rights reserved.
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页码:7005 / &
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