A NEW BONDING MODEL FOR OLEFINIC AND ACETYLENIC COMPLEXES OF TRANSITION METALS

被引：71

作者：

NELSON, JH

WHEELOCK, KS

CUSACHS, LC

JONASSEN, HB

机构：

[1] Richardson Chemistry Laboratories, Tulane University, New Orleans

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Semiempirical one-electron molecular orbital calculations were performed for a series of platinum-acetylene and -olefin complexes. The results indicate that the Dewar-Chatt-Duncanson model can be modified and extended to include the acetylenic complexes. A consistent hybridization scheme, dp2, is developed to explain the chemical and physical properties of these complexes. © 1969, American Chemical Society. All rights reserved.

引用

页码：7005 / &

共 25 条

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