ON THE APPLICABILITY OF THE KASHA-VAVILOV RULE TO C-60

被引：26

作者：

WILLIAMS, RM ^{[1
]}

VERHOEVEN, JW ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ORGAN CHEM LAB,NIEUWE ACHTERGRACHT 129,1018 WS AMSTERDAM,NETHERLANDS

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 02期

关键词：

D O I：

10.1016/0584-8539(94)80053-7

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Via full correction for the instrumental response function, the fluorescence excitation spectrum of C60 in methylcyclohexane between 240 and 580 nm is shown to match the absorption spectrum. This proves that, in contrast to earlier reports, also after UV excitation into higher S(n) states, deactivation proceeds virtually completely via the S1 state, in accordance with the Kasha-Vavilov rule.

引用

页码：251 / 254

页数：4

共 18 条

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[10] LOW-LYING ELECTRONICALLY EXCITED-STATES OF C-60 AND C-70 AND MEASUREMENT OF THEIR PICOSECOND TRANSIENT ABSORPTION IN SOLUTION
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