COPPER(I) HALIDE CATALYZED SYNTHESIS OF ALKYL ARYL AND ALKYL HETEROARYL ETHERS

被引：118

作者：

KEEGSTRA, MA ^{[1
]}

PETERS, THA ^{[1
]}

BRANDSMA, L ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT PREPARAT ORGAN CHEM,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS

来源：

TETRAHEDRON | 1992年 / 48卷 / 17期

关键词：

D O I：

10.1016/S0040-4020(01)88501-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of alkyl aryl and alkyl heteroaryl ethers have been prepared from (hetero) aryl halides (mainly bromides) and sodium alkoxides, using copper(I)bromide as a catalyst. The influence of the main solvent, the halogen atom, reaction temperature and the presence of oxygen upon the rate and selectivity has been studied. Furthermore the decomposition of the catalyst and the reduction of the aryl halide are studied.

引用

页码：3633 / 3652

页数：20

共 60 条

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