OXIDATIONS OF DIHYDROXYALKANOATES TO VICINAL TRICARBONYL COMPOUNDS WITH A 4-BZOTEMPO-SODIUM BROMITE SYSTEM OR BY INDIRECT ELECTROLYSIS USING 4-BZOTEMPO AND BROMIDE ION

被引：26

作者：

INOKUCHI, T ^{[1
]}

LIU, P ^{[1
]}

TORII, S ^{[1
]}

机构：

[1] OKAYAMA UNIV, FAC ENGN, DEPT APPL CHEM, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 08期

关键词：

D O I：

10.1246/cl.1994.1411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient access to vicinal dioxoalkanoates, one of structural elements of potent competitive inhibitors of hydrolytic enzyme, from 2,3-dihydroxyalkanoates has been developed, which features an one-step procedure with a mild oxidizing system using recyclable 2, 2, 6, 6-tetramethylpiperidine-1-oxyl in combination with NaBrO2.3H(2)O or electrogenerated active bromine species as a real oxidant.

引用

页码：1411 / 1414

页数：4

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