SUPERBASE-TRANSITION METAL BIFUNCTIONAL CATALYSTS IN CARBON-MONOXIDE HYDROGENATION AND AMMONIA-SYNTHESIS

被引：4

作者：

KIJENSKI, J

机构：

[1] Chemical Faculty, Laboratory of Catalytic Synthesis, Warsaw Technical University (Politechnika), Warsaw, 00-662

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1992年 / 46卷 / 01期

关键词：

D O I：

10.1007/BF02096684

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CO hydrogenation and NH3 synthesis at 300-degrees-C under normal pressure have been studied over a series of superbase-transition metal catalysts. A remarkable shift of selectivity toward longer carbon chain formation in CO conversion and an increase of NH3 yield were noted when compared with pure transition metal-supported catalysts activity.

引用

页码：99 / 106

页数：8

共 11 条

[1] AMMONIA SYNTHESIS OVER RHODIUM, IRIDIUM AND PLATINUM PROMOTED BY POTASSIUM
AIKA, K
YAMAGUCHI, J
OZAKI, A
[J]. CHEMISTRY LETTERS, 1973, (02) : 161 - 164
[2] ACTIVATION OF NITROGEN BY ALKALI-METAL PROMOTED TRANSITION-METAL .1. AMMONIA SYNTHESIS OVER RUTHENIUM PROMOTED BY ALKALI-METAL
AIKA, K
OZAKI, A
HORI, H
[J]. JOURNAL OF CATALYSIS, 1972, 27 (03) : 424 - &
[3] SUPPORT AND PROMOTER EFFECT OF RUTHENIUM CATALYST .1. CHARACTERIZATION OF ALKALI-PROMOTED RUTHENIUM ALUMINA CATALYSTS FOR AMMONIA-SYNTHESIS
AIKA, K
SHIMAZAKI, K
HATTORI, Y
OHYA, A
OHSHIMA, S
SHIROTA, K
OZAKI, A
[J]. JOURNAL OF CATALYSIS, 1985, 92 (02) : 296 - 304
[4] AMMONIA-SYNTHESIS OVER ALUMINA AND MAGNESIA SUPPORTED RUTHENIUM - COMPARATIVE KINETIC-STUDY OF THE PROMOTIVE ACTION OF METALLIC AND IONIC POTASSIUM
BARIS, H
GLINSKI, M
KIJENSKI, J
WOKAUN, A
BAIKER, A
[J]. APPLIED CATALYSIS, 1986, 28 (1-2): : 295 - 301
[5] GLINSKI M, 1983, PREPARATION CATALYST, V3, P554
[6] KIJENSKI J, 1981, B ACAD POL SCI-CHIM, V29, P23
[7] THE CARBON-MONOXIDE HYDROGENATION OVER SUPERBASIC AND SUPERBASE FERROUS METAL BIFUNCTIONAL CATALYSTS
KIJENSKI, J
GLINSKI, M
PEPLONSKI, R
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 25 (1-3): : 227 - 239
[8] INFLUENCE OF SODIUM ON PHYSICOCHEMICAL AND CATALYTIC PROPERTIES OF MAGNESIUM-OXIDE
KIJENSKI, J
MALINOWSKI, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 : 250 - 261
[9] KIJENSKI J, 1981, REACT KINET CATAL L, V18, P233
[10] KIJENSKI J, 1980, J RES I CAT HOKKAIDO, V28, P97

← 1 2 →