HOMOGENEOUS CATALYSIS - [TICP2(CF3SO3)2] AND [ZRCP2(CF3SO3)2THF], FAST AND EFFICIENT CATALYSTS FOR THE MUKAIYAMA CROSS-ALDOL REACTION

被引：62

作者：

HOLLIS, TK ^{[1
]}

ROBINSON, NP ^{[1
]}

BOSNICH, B ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT CHEM,5735 S ELLIS AVE,CHICAGO,IL 60637

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 43期

关键词：

CROSS-ALDOL CATALYSIS; TITANIUM AND ZIRCONIUM CATALYSTS; ADDUCT FORMATION;

D O I：

10.1016/S0040-4039(00)79005-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalysts [TiCp2(CF3SO3)2] and [ZrCP2(CF3SO3)2THF] are fast and efficient catalysts for the Mukaiyama cross-aldol reaction involving both ketones and aldehydes and the catalysis is promoted by binding of the carbonyl group to the metal after dissociation of triflato ligands.

引用

页码：6423 / 6426

页数：4

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