SYNTHESIS, CRYSTAL, MOLECULAR AND ELECTRONIC-STRUCTURE OF A NOVEL HETEROBINUCLEAR ALKOXIDE CLUSTER - [(MEO)(2)REO(MU-OME)(3)MOO(OME)(2)]

被引：19

作者：

KESSLER, VG ^{[1
]}

SEISENBAEVA, GA ^{[1
]}

SHEVELKOV, AV ^{[1
]}

KHVORYKH, GV ^{[1
]}

机构：

[1] MV LOMONSOV STATE ACAD FINE CHEM TECHNOL,MOSCOW 117571,RUSSIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001779

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new heterobimetallic methoxide [ReMoO2(OMe)(7)] 1 is obtained in 62% yield by hexane extraction from the electrolyte prepared by anodic oxidation of Re metal in a methanolic solution of [MoO(OMe)(4)] in the presence of LiCl as electrolyte; the molecule of 1 consists of two [MO(OMe)(5)] octahedra with three shared mu-OMe groups; while 1 shows high volatility and under such conditions remains intact, mass spectrometry indicates complete dissociation into homometallic species in the gas phase.

引用

页码：1779 / 1780

页数：2

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