NEW INTERMEDIATE STEPS IN THE SYNTHESIS OF LARGER NICKEL CLUSTERS

被引：44

作者：

FENSKE, D

KRAUTSCHEID, H

MULLER, M

机构：

[1] Institut Für Anorganische Chemie Der, Universität Engesserstrasse, Karlsruhe, D-W-7500

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphane complexes of NiCl2 react with Se(SiMe3)2 affording mixtures of cluster complexes whose structures are dependent on the phosphane ligands. Through the variation of the ligands, complexes 1-6 were isolated and structurally characterized (Phe = C2H4Ph). Cluster 2 incorporates a spirocyclic Ni5 framework, 6 a central Ni13 cuboctahedron.

引用

页码：321 / 323

页数：3

共 35 条

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