NEW INTERMEDIATE STEPS IN THE SYNTHESIS OF LARGER NICKEL CLUSTERS

被引：44

作者：

FENSKE, D

KRAUTSCHEID, H

MULLER, M

机构：

[1] Institut Für Anorganische Chemie Der, Universität Engesserstrasse, Karlsruhe, D-W-7500

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphane complexes of NiCl2 react with Se(SiMe3)2 affording mixtures of cluster complexes whose structures are dependent on the phosphane ligands. Through the variation of the ligands, complexes 1-6 were isolated and structurally characterized (Phe = C2H4Ph). Cluster 2 incorporates a spirocyclic Ni5 framework, 6 a central Ni13 cuboctahedron.

引用

页码：321 / 323

页数：3

共 35 条

[21] CARBON COMPOUNDS OF TRANSITION METALS .11. STRUCTURE OF (DIPHENYLACETYLENE)BIS(CYCLOPENTADIENYLNICKEL)
MILLS, OS
SHAW, BW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 11 (03) : 595 - &
[22] POLYHEDRAL SKELETAL ELECTRON PAIR APPROACH
MINGOS, DMP
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1984, 17 (09) : 311 - 319
[23] MINGOS DMP, 1987, STRUCT BOND, V68, P29
[24] POLYHEDRAL SKELETAL ELECTRON PAIR APPROACH - A GENERALIZED PRINCIPLE FOR CONDENSED POLYHEDRA
MINGOS, DMP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (12) : 706 - 708
[25] THEORETICAL ANALYSES AND ELECTRON COUNTING RULES FOR HIGH NUCLEARITY CLUSTERS
MINGOS, DMP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (19) : 1352 - 1354
[26] BONDING IN MOLECULAR CLUSTERS AND THEIR RELATIONSHIP TO BULK METALS
MINGOS, DMP
[J]. CHEMICAL SOCIETY REVIEWS, 1986, 15 (01) : 31 - 61
[27] MINGOS DMP, 1985, J ORGANOMET CHEM, V280, P419
[28] MULLER M, UNPUB
[29] SCHMID G, 1985, STRUCT BOND, V62, P51
[30] METAL-CLUSTERS AND CLUSTER METALS
SCHMID, G
[J]. POLYHEDRON, 1988, 7 (22-23) : 2321 - 2329

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