NOVEL TRINUCLEAR AND DINUCLEAR NICKEL COORDINATION-COMPOUNDS WITH A NEW PENTADENTATE LIGAND - CRYSTAL-STRUCTURES OF [NI3(BDNOL)(ETOH)CL5] AND [NI2(BDNOL)CL3]

被引：12

作者：

BOUWMAN, E ^{[1
]}

EVANS, P ^{[1
]}

KOOIJMAN, H ^{[1
]}

REEDIJK, J ^{[1
]}

SPEK, AL ^{[1
]}

机构：

[1] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES CRYSTAL & STRUCT CHEM,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 23期

关键词：

D O I：

10.1039/c39930001746

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pentadentate ligand 1,9-bis(3,5-dimethyl-1-pyrazolyl)-3,7-dithianonan-5-ol (Hbdnol) yields, with nickel chloride, the unique trinuclear compound [Ni3(bdnol)(EtOH)Cl5] with two [NiNSOCl3] and one [NiCl4OO'] distorted octahedral chromophores, and the dinuclear compound [Ni2(bdnol)Cl3], with two [NiNSOCl2] distorted trigonal bipyramidal chromophores.

引用

页码：1746 / 1748

页数：3