STEREOSELECTIVE CONSTRUCTION OF THE COMPLETE INGENANE RING-SYSTEM

被引：38

作者：

FUNK, RL

OLMSTEAD, TA

PARVEZ, M

STALLMAN, JB

机构：

[1] Department of Chemistry, The Pennsylvania State University, Pennsylvania 16802, University Park

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 22期

关键词：

D O I：

10.1021/jo00074a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective route to the fully assembled and optically pure tetracyclic ring system of ingenol which features a macrocyclic Claisen rearrangement for the construction of the strained in,out-bridged bicyclic substructure and simultaneous, strategic placement of functionality has been developed.

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页码：5873 / 5875

页数：3

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