SEMICLASSICAL AND QUANTUM-MECHANICAL PICTURES OF THE RO-VIBRATIONAL MOTION OF TRIATOMIC-MOLECULES

被引：46

作者：

MAKAREWICZ, J

机构：

[1] A. Mickiewicz University, Poznań

来源：

MOLECULAR PHYSICS | 1990年 / 69卷 / 05期

关键词：

D O I：

10.1080/00268979000100681

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Qualitative and quantitative aspects of the semiclassical method using rotational energy surfaces, are studied. These surfaces are determined for triatomic molecules by applying the rigid-bender model. A relation between the topology of the rotational energy surfaces and the structure of rotational multiplets is analysed. The semiclassical tools are used to determine properties of quantum ro-vibrational states. © 1990 Taylor & Francis Ltd.

引用

收藏

页码：903 / 921

页数：19

相关论文

共 24 条

[1] INFRARED SPECTRUM OF HYDROGEN SULFIDE FROM 2200-2800-CM-1 [J].

ALLEN, HC ;

BLAINE, LR ;

PLYER, EK .

JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (01) :35-38

[2] Remarks on undulatory mechanics [J].

Brillouin, L .

JOURNAL DE PHYSIQUE ET LE RADIUM, 1926, 7 :353-368

[3]

EINSTEIN A, 1917, VERHAND DEUT PHYS GE, V19, P82

[4] INTERACTION BETWEEN BENDING VIBRATIONS AND MOLECULAR ROTATION - A MODEL STUDY [J].

EZRA, GS .

CHEMICAL PHYSICS LETTERS, 1986, 127 (05) :492-500

[5] UNIFORM SEMICLASSICAL QUANTIZATION OF MULTIDIMENSIONAL SYSTEMS - APPLICATION TO VIBRATION-ROTATION EIGENVALUES [J].

FREDERICK, JH .

CHEMICAL PHYSICS LETTERS, 1986, 131 (1-2) :60-64

[6] NONLINEAR DYNAMICS OF VIBRATION-ROTATION INTERACTIONS - RIGID BENDER H2O [J].

FREDERICK, JH ;

MCCLELLAND, GM .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (08) :4347-4363

[7] SEMICLASSICAL QUANTIZATION OF THE VIBRATION-ROTATION PROBLEM [J].

FREDERICK, JH ;

MCCLELLAND, GM .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (02) :876-890

[8]

GILLIS JR, 1981, J MOL SPECTROSC, V85, P74, DOI 10.1016/0022-2852(81)90310-6

[9] COMPUTER GRAPHICAL AND SEMICLASSICAL APPROACHES TO MOLECULAR ROTATIONS AND VIBRATIONS [J].

HARTER, WG .

COMPUTER PHYSICS REPORTS, 1988, 8 (06) :319-394

[10] ROTATIONAL ENERGY SURFACES AND HIGH-J EIGENVALUE STRUCTURE OF POLYATOMIC-MOLECULES [J].

HARTER, WG ;

PATTERSON, CW .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4241-4261