SEMICLASSICAL AND QUANTUM-MECHANICAL PICTURES OF THE RO-VIBRATIONAL MOTION OF TRIATOMIC-MOLECULES

被引：46

作者：

MAKAREWICZ, J

机构：

[1] A. Mickiewicz University, Poznań

来源：

MOLECULAR PHYSICS | 1990年 / 69卷 / 05期

关键词：

D O I：

10.1080/00268979000100681

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Qualitative and quantitative aspects of the semiclassical method using rotational energy surfaces, are studied. These surfaces are determined for triatomic molecules by applying the rigid-bender model. A relation between the topology of the rotational energy surfaces and the structure of rotational multiplets is analysed. The semiclassical tools are used to determine properties of quantum ro-vibrational states. © 1990 Taylor & Francis Ltd.

引用

收藏

页码：903 / 921

页数：19

相关论文

共 24 条

[11] VIBRATION-ROTATION PROBLEM IN TRIATOMIC MOLECULES ALLOWING FOR A LARGE-AMPLITUDE BENDING VIBRATION [J].

HOUGEN, JT ;

BUNKER, PR ;

JOHNS, JWC .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1970, 34 (01) :136-&

[12] CORRECTED BOHR-SOMMERFELD QUANTUM CONDITIONS FOR NONSEPARABLE SYSTEMS [J].

KELLER, JB .

ANNALS OF PHYSICS, 1958, 4 (02) :180-188

[13] REDUCED DENSITY-MATRICES AND REDUCED LOCAL OPERATORS FOR A ROTATING-VIBRATING MOLECULE [J].

MAKAREWICZ, J .

MOLECULAR PHYSICS, 1989, 66 (01) :113-127

[14] SELF-CONSISTENT APPROACH TO THE BENDING-ROTATION INTERACTIONS IN THE H2O MOLECULE [J].

MAKAREWICZ, J .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1988, 130 (02) :316-336

[15] COMPUTATION OF GENERALIZED SPHEROIDAL EIGENFUNCTIONS AND EIGENVALUES [J].

MAKAREWICZ, J .

JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1989, 22 (18) :4089-4097

[16] EXACT SOLVABLE QUANTUM MODELS OF ROTATING-VIBRATING TRIATOMIC-MOLECULES [J].

MAKAREWICZ, J .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1988, 21 (22) :3633-3651

[17]

MARKAREWICZ J, 1989, MOL PHYS, V68, P107

[18] SIMULTANEOUS ANALYSIS OF 2NU1 AND NU1+NU3 BANDS AND EQUILIBRIUM STRUCTURE OF HYDROGEN TELLURIDE [J].

MONCUR, NK ;

WILLSON, PD ;

EDWARDS, TH .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 52 (03) :380-391

[19] CRITICAL PHENOMENA IN ROTATIONAL SPECTRA [J].

PAVLICHENKOV, IM ;

ZHILINSKII, BI .

ANNALS OF PHYSICS, 1988, 184 (01) :1-32

[20] ROTATION OF MOLECULES AROUND SPECIFIC AXES - AXES REORIENTATION UNDER ROTATIONAL-EXCITATION [J].

PAVLICHENKOV, IM ;

ZHILINSKII, BI .

CHEMICAL PHYSICS, 1985, 100 (03) :339-354