SIDE ARM EFFECTS ON CATION-BINDING, EXTRACTION, AND TRANSPORT FUNCTIONS OF OLIGOPYRIDINE-FUNCTIONALIZED AZA-CROWN ETHERS

被引：79

作者：

TSUKUBE, H ^{[1
]}

UENISHI, J ^{[1
]}

HIGAKI, H ^{[1
]}

KIKKAWA, K ^{[1
]}

TANAKA, T ^{[1
]}

WAKABAYASHI, S ^{[1
]}

OAE, S ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,FAC SCI,DEPT CHEM,OKAYAMA 700,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 16期

关键词：

D O I：

10.1021/jo00068a038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new series of lariat ethers and double-armed crown ethers was prepared in which oligopyridine-functionalized side arms were attached as secondary donor sites. A novel preparative method of oligopyridine derivatives was successfully applied to the synthesis of these crown ethers. Introduction of an oligopyridine-functionalized side arm into the crown ether system, if of the proper chain length and geometrical arrangement, significantly offered three-dimensional complexation with various metal cations suitable for extraction and transport. Liquid-liquid extraction, C-13-NMR binding, and liquid membrane transport experiments revealed that the present type of double-armed crown ethers exhibited cation-binding abilities superior to corresponding lariat ethers.

引用

页码：4389 / 4397

页数：9

共 30 条

[21] LANTHANIDE COMPLEX WITH ARMED CROWN-ETHER AS HETEROTOPIC CARRIER OF HYDROPHILIC AMINO-ACID ESTER SALTS [J].