A Simple Empirical Equation for the Prediction of the Activity-Coefficient Value of Each Component in Aqueous Electrolyte Mixtures Containing a Common Ion

被引：58

作者：

Lietzke, M. H. ^{[1
]}

Stoughton, R. W. ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem, Oak Ridge, TN 37831 USA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1972年 / 1卷 / 04期

关键词：

Activity coefficient; electrolyte mixtures; aqueous solutions; electrolytes; chloride solutions;

D O I：

10.1007/BF00715989

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple empirical equation is presented for the prediction of the mean ionic activity coefficient of each component in aqueous electrolyte mixtures containing a common ion. The results obtained in a variety of two- and three-electrolyte mixtures show that in most cases log gamma values predicted by this equation are consistent with values predicted using an elaborate ion-component model.

引用

页码：299 / 308

页数：10

共 15 条

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[7] ELECTROMOTIVE FORCE STUDIES IN AQUEOUS SOLUTIONS AT ELEVATED TEMPERATURES .12. THERMODYNAMIC PROPERTIES OF HCL-CSCL-BACL2 MIXTURES
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[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1969, 31 (11): : 3481 - &
[8] LIETZKE MH, 1964, J TENNESSEE ACAD SCI, V39, P30
[9] LINDENBAUM SJ, COMMUNICATION
[10] PREDICTION OF OSMOTIC AND ACTIVITY COEFFICIENTS IN MIXED-ELECTROLYTE SOLUTIONS
REILLY, PJ
WOOD, RH
ROBINSON, RA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (09) : 1305 - &

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