CONFORMATIONAL STUDIES BY DYNAMIC NMR .49. THE HIGH ROTATION BARRIER AND LOWER NITROGEN INVERSION ROTATION BARRIER IN N,N-DIISOBUTYL-2,4-DIMETHYL-3-PENTYLAMINE

被引：12

作者：

CASARINI, D

LUNAZZI, L

ANDERSON, JE

机构：

[1] UNIV BOLOGNA,DEPT ORGAN CHEM A MANGINI,RISORGIMENTO 4,I-40136 BOLOGNA,ITALY

[2] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1E 6BT,ENGLAND

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 03期

关键词：

D O I：

10.1021/jo00055a028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The temperature dependence of the C-13 and H-1 NMR spectra of the title compound is reported and discussed in terms of a rotation about the dimethylpentyl to nitrogen bond, with a barrier of 9.4 kcal mol-1 and a lower barrier of 7.9 kcal mol-I to nitrogen inversion/rotation.

引用

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页码：714 / 717

页数：4

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