THERMODYNAMIC INVESTIGATION OF COPPER + SILICON MELTS

被引：34

作者：

CASTANET, R

机构：

[1] Centre de Thermodynamique et de Microcalorimétrie, C.N.R.S., Section de Thermodynamique des alliages, 13003 Marseille

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1979年 / 11卷 / 08期

关键词：

D O I：

10.1016/0021-9614(79)90010-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The enthalpy of formation of copper + silicon liquid alloys has been measured at 1370 K by direct reaction calorimetry. The enthalpy of formation is negative in the whole range of composition and has a minimum -(14.35 ± 0.3) kJ mol-1, for a mole fraction x(Si) = 0.25. From the thermodynamic behaviour of the melts, the assumption was made that the metastable deep eutectic between pure Cu and Si can be explained by chemical bonding around Cu3Si. © 1979.

引用

页码：787 / 791

页数：5