POLYACRYLAMIDE GELS AS ELASTIC MODELS FOR FOOD GELS

被引:38
作者
FOEGEDING, EA
GONZALEZ, C
HAMANN, DD
CASE, S
机构
[1] UNIV BARCELONA,DEPT ENGN QUIM,BARCELONA 7,SPAIN
[2] NATL STARCH & CHEM CORP,BRIDGEWATER,NJ
关键词
D O I
10.1016/S0268-005X(09)80038-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The physical properties of polyacrylamide gels (10% w/v) were evaluated by dynamic oscillatory testing, stress relaxation and torsional fracture analysis. Gels had a linear relationship between shear stress and strain when deformed to fracture; thus small strain (storage modulus, G;) and large strain (fracture modulus. Gf) moduli were equivalent, Non-fracture and fracture tests showed that gels maintained an entropy (rubber) elastic response over all testing temperatures (10-80-degrees-C). Shear stress at fracture was independent of temperature. whereas shear strain at fracture decreased as temperature increased. This was associated with increased thermal motion strains decreasing the amount of mechanically induced strain required for fracture. Our results have shown that polyacrylamide gels are a suitable elastic model tor understanding the molecular mechanisms of food texture.
引用
收藏
页码:125 / 134
页数:10
相关论文
共 26 条
[1]  
[Anonymous], 1980, VISCOELASTIC PROPERT
[2]   PROGEL AND GEL FORMATION AND REVERSIBILITY OF GELATION OF WHEY, SOYBEAN, AND ALBUMIN PROTEIN GELS [J].
BEVERIDGE, T ;
JONES, L ;
TUNG, MA .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1984, 32 (02) :307-313
[3]   MOLECULAR THEORY FOR TENSILE STRENGTH OF GUM ELASTOMERS [J].
BUECHE, F ;
HALPIN, JC .
JOURNAL OF APPLIED PHYSICS, 1964, 35 (01) :36-&
[4]  
Case S. E., 1992, GUMS STABILIZERS FOO, V6, P489
[5]  
CASE SE, 1994, IN PRESS FOOD HYDROC, V8
[6]  
CLARK AH, 1987, ADV POLYM SCI, V83, P60
[7]   STRUCTURAL FAILURE IN SELECTED RAW FRUITS AND VEGETABLES [J].
DIEHL, KC ;
HAMANN, DD ;
WHITFIELD, JK .
JOURNAL OF TEXTURE STUDIES, 1980, 10 (04) :371-400
[8]  
EBELER SE, 1990, MILCHWISSENSCHAFT, V45, P694
[9]   RHEOLOGICAL PROPERTIES OF WHEY-PROTEIN ISOLATE GELS DETERMINED BY TORSIONAL FRACTURE AND STRESS-RELAXATION [J].
FOEGEDING, EA .
JOURNAL OF TEXTURE STUDIES, 1992, 23 (03) :337-348
[10]   SPECIFIC DIVALENT CATION-INDUCED CHANGES DURING GELATION OF BETA-LACTOGLOBULIN [J].
FOEGEDING, EA ;
KUHN, PR ;
HARDIN, CC .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1992, 40 (11) :2092-2097