THE BOND-LENGTH OF COKR+

被引：17

作者：

BUTHELEZI, T ^{[1
]}

BELLERT, D ^{[1
]}

LEWIS, V ^{[1
]}

BRUCAT, PJ ^{[1
]}

机构：

[1] UNIV FLORIDA,CTR CHEM PHYS,GAINESVILLE,FL 32611

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 242卷 / 06期

关键词：

D O I：

10.1016/0009-2614(95)00789-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotationally resolved photodissociation spectra of CoKr+ have been observed for an electronic transition in the isolated ion. Analysis yields rotational, constants and the angular momentum (spin plus orbit) for both states in the transition. The bond length in vibrationless level of the ground state of this ion is determined to be r(0) = 2.447 +/- 0.005 Angstrom with a rotational structure consistent with a (3) Delta(3) electronic state. Excited-state diabatic dissociation limits enable the determination of the adiabatic binding energy of ground state of CoKr+ as D-0 = 5405 +/- 15 cm(-1). These data are discussed in comparison with similar observations in CoAr+ and CoXe+.

引用

页码：627 / 631

页数：5

共 7 条

[1] THE GROUND-STATE OF COAR(+) [J].