PREPARATION OF NEW INDANDIONE ANALOGUES .5. NITRO AND AMINO DERIVATIVES OF INDANDIONE ANALOGUE FROM DIPHENIC ANHYDRIDE AND PHENYLACETIC ACID

被引：13

作者：

ALEKSIEV, B

MILOSEV, M

机构：

[1] Lehrstuhl für organische Chemie des Höheren chemisch-technologischen Instituts

来源：

MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 06期

关键词：

D O I：

10.1007/BF01151755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nitration of the indandione analogue 1 with conc. HNO3 afforded a mononitro derivative (2b) in very good yield, the nitro group substituting the H atom in the methine group of the 7membered diketone ring. Upon reduction this nitro compound gave a dimeric amino derivative (7). When the halogenated derivatives of 1 were treated with NH3 in order to replace the halogen by an amino group, a ketimino derivative (5) was isolated. © 1969 Springer-Verlag.

引用

页码：2024 / &