THE 6 ECLIPSED SIDE-CHAINS IN SCYLLO-INOSITOL HEXAMETHYL ETHER - A MOLECULAR MECHANICS STUDY

被引：19

作者：

ANDERSON, JE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 03期

关键词：

D O I：

10.1039/p29930000441

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The most stable conformation of the hexamethyl ether of scyllo-inositol (all-trans-cyclohexan-1,2,3,4,5,6-hexol) is calculated to be the one with six equatorial methoxy groups with in each case the oxygen-methyl bond eclipsing the adjacent axial carbon-hydrogen bond. Eclipsed bonds are also calculated for other inositol hexamethyl ether stereoisomers. Results contrast with the conformations of the equivalent hexaethylcyclohexane.

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页码：441 / 443

页数：3

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