THE 6 ECLIPSED SIDE-CHAINS IN SCYLLO-INOSITOL HEXAMETHYL ETHER - A MOLECULAR MECHANICS STUDY

被引：19

作者：

ANDERSON, JE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 03期

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D O I：

10.1039/p29930000441

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The most stable conformation of the hexamethyl ether of scyllo-inositol (all-trans-cyclohexan-1,2,3,4,5,6-hexol) is calculated to be the one with six equatorial methoxy groups with in each case the oxygen-methyl bond eclipsing the adjacent axial carbon-hydrogen bond. Eclipsed bonds are also calculated for other inositol hexamethyl ether stereoisomers. Results contrast with the conformations of the equivalent hexaethylcyclohexane.

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页码：441 / 443

页数：3

相关论文

共 25 条

[11] THE MOLECULAR STRUCTURE OF METHYL ALCOHOL [J].

BURKHARD, DG ;

DENNISON, DM .

PHYSICAL REVIEW, 1951, 84 (03) :408-417

[12] AXIAL EQUATORIAL STABILITY REVERSAL IN ALL-TRANS-POLYALKYLCYCLOHEXANES [J].

GOLAN, O ;

GOREN, Z ;

BIALI, SE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9300-9307

[13] VIBRATION-HINDERED ROTATION INTERACTIONS IN METHYL ALCOHOL - J=0-]1 TRANSITION [J].

HECHT, KT ;

DENNISON, DM .

JOURNAL OF CHEMICAL PHYSICS, 1957, 26 (01) :48-69

[14] BARRIER TO INTERNAL-ROTATION IN ETHANE FROM THE MICROWAVE-SPECTRUM OF CH3CHD2 [J].

HIROTA, E ;

SAITO, S ;

ENDO, Y .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (03) :1183-1187

[15]

IMMIRZI A, 1968, ATTI ACCAD NAZ LIN, V44, P98

[16] THE METHYL ALCOHOL MOLECULE AND ITS MICROWAVE SPECTRUM [J].

IVASH, EV ;

DENNISON, DM .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (10) :1804-1816

[17] INCLUSION COMPOUND DESIGN - THE PIEDFORT CONCEPT [J].

JESSIMAN, AS ;

MACNICOL, DD ;

MALLINSON, PR ;

VALLANCE, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1619-1621

[18] The entropy of ethane and the third law of thermodynamics hindered rotation of methyl groups [J].

Kemp, JD ;

Pitzer, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :276-279

[19]

MACNICOL DD, 1984, INCLUSION COMPOUNDS, V2, pCH5

[20] FINE STRUCTURE OF J=1]-O TRANSITION DUE TO INTERNAL ROTATION IN METHYL ALCOHOL [J].

NISHIKAWA, T .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1956, 11 (07) :781-786